Methylmagnesium chloride solution, 3.0 M in THF

Code: 189901-100ML D2-231

Application

Methylmagnesium chloride solution (3 M in THF) undergoes 1,3-addition with dialdose derived nitrones to form N-benzylhydroxylamines. The reductive cleava...


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€67.60 100ML
€83.15 inc. VAT
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Application

Methylmagnesium chloride solution (3 M in THF) undergoes 1,3-addition with dialdose derived nitrones to form N-benzylhydroxylamines. The reductive cleavage of the N-O bond of these N-benzylhydroxylamines results in N-benzylaminosugars, which are key moieties of bioactive compounds. It can also react with Garner type aldehydes to form the corresponding secondary alcohols.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Packaging

4×25, 100, 800 mL in Sure/Seal™

8, 18 L in Kilo-Lab™

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The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

autoignition temp.609 °F
concentration3.0 M in THF
density1.013 g/mL at 25 °C
InChI keyRQNMYNYHBQQZSP-UHFFFAOYSA-M
InChI1S/CH3.ClH.Mg/h1H3;1H;/q;;+1/p-1
Quality Level200
reaction suitabilityreaction type: Grignard Reaction
SMILES stringC[Mg]Cl
Cas Number676-58-4
Hazard Class4.3
Un Number3399
Pack GroupII
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